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RodA has been shown to form a robust, protein monolayer on the surface of the Aspergillus fumigatus conidia. It was found that during ECD complexes with many metal atoms do not dissociate and only decrease their charge by capturing the electron. Our recent advances fill this critical knowledge gap. Recently we have reported the supermetallization phenomenon, which is the formation of complex ions of peptide—metal in the gas phase when the peptide accepts an unexpectedly large number of metal atoms.